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Product Details
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General Description |
Iron(1+), (.eta.5-2,4-cyclopentadien-1-yl)(1,2,3,4,5,6-.eta.)-(1-methylethyl)benzene-, hexafluorophosphate(1-) is a chemical compound containing iron in the +1 oxidation state. It is a complex with a cyclopentadienyl ligand and a hexafluorophosphate counterion. The cyclopentadienyl ligand is bonded to the iron atom through five carbon atoms, while the (1-methylethyl)benzene ligand is bonded through all six carbon atoms. The hexafluorophosphate ion carries a charge of -1 and balances the charge of the iron cation. Iron(1+), (.eta.5-2,4-cyclopentadien-1-yl)(1,2,3,4,5,6-.eta.)-(1-methylethyl)benzene-, hexafluorophosphate(1-) is commonly used in coordination chemistry and organometallic synthesis as a source of iron(1+) in various reactions and processes. |
InChI:InChI=1/C9H12.C6H7.6FH.Fe.P/c1-8(2)9-6-4-3-5-7-9;1-2-4-6-5-3-1;;;;;;;;/h3-8H,1-2H3;1-5H,6H2;6*1H;;/q;-1;;;;;;;+2;+5/p-6
The reactivity of O2.- generated in iner...
hexafluorophosphoric acid
{(Cp)iron(II)(η5-C6H5(isopropyl)O)}2
(η6-cumene)(η5-cyclopentadienyl)iron hexafluorophosphate
| Conditions | Yield |
|---|---|
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In
diethyl ether;
byproducts: H2O2; The dimeric peroxide complex is hydrolyzed by HPF6 at -80°C under dry N2.; characterization by (1)H NMR;
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50% |
sodium hexaflorophosphate
{(Cp)iron(I)(η6-isopropylbenzene)}
sodium peroxide
(η6-cumene)(η5-cyclopentadienyl)iron hexafluorophosphate
| Conditions | Yield |
|---|---|
|
With
oxygen;
In
tetrahydrofuran;
addn. of O2 at -80°C under dry N2;
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{(Cp)iron(I)(η6-isopropylbenzene)}
CAS：100011-37-8
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