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Product Details
The invention relates to a preparation m...
We describe a new functional group metat...
The present invention refers to a proces...
The invention discloses a synthetic meth...
morpholine
2-methoxy-3,3-dimethyl-2-(4-methylthiophenyl)oxirane
2-methyl-1-[4-(methylthio)phenyl]-2-morpholinopropan-1-one
Conditions | Yield |
---|---|
With calcium hydroxide; at 20 - 138 ℃; for 20h;
|
90.2% |
With tetra(n-butyl)ammonium hydrogensulfate; sodium hydroxide; for 8h; Reflux;
|
43% |
at 105 - 110 ℃; for 20h; Temperature;
|
119.3 g |
at 105 - 115 ℃; for 20h;
|
112.57 g |
With water; at 105 ℃; for 12h; Reagent/catalyst; Large scale;
|
morpholine
2-bromo-2-methyl-1-[4-(methylsulfanyl)phenyl]propan-1-one
2-methyl-1-[4-(methylthio)phenyl]-2-morpholinopropan-1-one
Conditions | Yield |
---|---|
morpholine; With aluminum (III) chloride; In 1,2-dichloro-ethane; at 40 ℃; for 0.5h;
2-bromo-2-methyl-1-[4-(methylsulfanyl)phenyl]propan-1-one; In 1,2-dichloro-ethane; at 40 ℃; for 6h;
|
60.57% |
morpholine
2-bromo-2-methyl-1-[4-(methylsulfanyl)phenyl]propan-1-one
2-methyl-1-(4-(methylthio)phenyl)-propan-1-one
methyl-phenyl-thioether
2-morpholino propan-2-yl radical
C8H7OS
dimethyl-[4-(2-methyl-2-morpholino-propanoyl)phenyl]sulfonium methyl sulfate
2-methyl-1-(4-methylsulfanylphenyl)-2-morpholin-4-ium-4-yl-propan-1-one chloride
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