15206-55-0

  • Product NameMethyl benzoylformate
  • Molecular FormulaC9H8O3
  • Molecular Weight164.161
  • Purity99%
  • Appearancelight yellow liquid
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Product Details

Quick Details

  • CasNo: 15206-55-0
  • Molecular Formula: C9H8O3
  • Appearance: light yellow liquid
  • Purity: 99%

Chemical plants supply high-quality Methyl benzoylformate 15206-55-0 in bulk

  • Molecular Formula:C9H8O3
  • Molecular Weight:164.161
  • Appearance/Colour:light yellow liquid 
  • Vapor Pressure:0.0263mmHg at 25°C 
  • Melting Point:16 °C 
  • Refractive Index:1.5260 
  • Boiling Point:247 °C at 760 mmHg 
  • Flash Point:103.8 °C 
  • PSA:43.37000 
  • Density:1.164 g/cm3 
  • LogP:1.04230 

Methyl benzoylformate(Cas 15206-55-0) Usage

Flammability and Explosibility

Notclassified

Purification Methods

Purify the ester by radial chromatography (diethyl ether/hexane, 1:1), and dry it at 110-112o/6mm. [Meyers & Oppenlaender J Am Chem Soc 108 1989 1986, Beilstein 10 IV 2738.]

Definition

ChEBI: The methyl ester of phenylglyoxylic acid with methanol. Metabolite observed in cancer metabolism.

InChI:InChI=1/C9H8O3/c1-12-9(11)8(10)7-5-3-2-4-6-7/h2-6H,1H3

15206-55-0 Relevant articles

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Photosensitized oxidation of tellurides ...

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Ohno et al.

, p. 21,26 (1977)

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Jefford,Barchietto

, p. 4531,4532 (1977)

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HALIDE-DIRECTED NITRILE HYDROLYSYS

Photis, James M.

, p. 3539 - 3540 (1980)

Sodium bromide is an effective catalyst ...

Air oxidation of p-substituted benzoin to the corresponding benzil catalyzed by Fe(II)-cysteine peptide complexes

Sun, Wei-Yin,Ueyama, Norikazu,Nakamura, Akira

, p. 1557 - 1566 (1992)

The Fe(II)-cysteine-containing peptide c...

Oxidations of Dihydroxyalkanoates to Vicinal Tricarbonyl Compounds with a 4-BzoTEMPO-Sodium Bromite System or by Indirect Electrolysis Using 4-BzoTEMPO and Bromide Ion

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, p. 1411 - 1414 (1994)

An efficient access to vicinal dioxoalka...

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Schaefer,Corey

, p. 1825 (1959)

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A novel method for synthesis of α-keto esters with phenyliodine(III) diacetate

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Novel Synthesis of α-Keto Esters and Amides by an sp3 C-H Oxidation of Nitromethyl Aryl Ketones Promoted by Ion-Supported (Diacetoxyiodo)benzene

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A simple and efficient method is describ...

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, p. 2427 - 2430 (2002)

α-Keto acid esters can be easily prepare...

A Tricomponent Reaction Promoted by a Titanium Trichloride/Pyridine System Diastereoselective Synthesis of β-Amino-α-hydroxyesters

Clerici, Angelo,Clerici, Laura,Porta, Ombretta

, p. 5955 - 5958 (1995)

Methyl phenylglyoxylate, aniline and aro...

5,10,15,20-Tetraphenylporphyrinatorhodium(III) iodide catalyzed cyclopropanation reactions of alkenes using glycine ester hydrochloride

Barrett, Anthony G. M.,Braddock, D. Christopher,Lenoir, Isabelle,Tone, Hitoshi

, p. 8260 - 8263 (2001)

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One-pot efficient synthesis of aryl α-keto esters from aryl-ketones

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, p. 9797 - 9800 (2009)

A novel one-pot synthesis of aryl α-keto...

Reactivity of methyl mandelate-Ti(IV)-enediolate: Oxidative homocoupling versus aldol and direct Mannich-type syn-diastereoselective condensation

Clerici, Angelo,Pastori, Nadia,Porta, Ombretta

, p. 4174 - 4176 (2005)

Methyl mandelate undergoes quantitative ...

Direct Access to 2-Thioxooxazolidin-4-ones and Oxazolidine-2,4-diones from α-Keto Thioesters through Thiolate Transfer

Maity, Rajib,Naskar, Sandip,Mal, Kanchan,Biswas, Sandipa,Das, Indrajit

, p. 4405 - 4410 (2017)

We report a direct synthesis of 2-thioxo...

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Baer,Kates

, p. 1482 (1945)

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Yadav, Ganapati D.,Bhagat, Ramesh D.

, p. 879 - 882 (2004)

Oxidation is an important class of react...

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, p. 2398 - 2404 (2006)

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Enantiospecific total synthesis of (+)-tanikolide via a key [2,3]-meisenheimer rearrangement with an allylic amine N-oxide-directed epoxidation and a one-pot trichloroisocyanuric acid N-debenzylation and N-chlorination

Xie, Yangla,Sun, Moran,Zhou, Hang,Cao, Qiwei,Gao, Kaige,Niu, Changling,Yang, Hua

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Mechanistic Investigation of the Oxidation of the Carbanion of Methyl 2-Methoxy-2-phenylacetate by an Isoalloxazine

Novak, Michael,Bruice, Thomas C.

, p. 372 - 374 (1980)

Evidence from product studies and radica...

Oxygenation of Phenylacetylene catalysed bu Co(salen)

Nishinaga, Akira,Maruyama, Kazushige,Yoda, Kohei,Okamoto, Hiromitsu

, p. 876 - 877 (1990)

Co(salen) catalysed oxygenation of 4-sub...

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Catir, Mustafa,Kilic, Hamdullah

, p. 1319 - 1322 (2010)

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Vanadium-catalysed Novel Oxidation of Arylacetic Esters for the Synthesis of Arylglyoxylic Esters

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, p. 323 - 324 (1993)

Direct synthesis of arylglyoxylic esters...

Oxidative Decarboxylation of Propiolic Acids

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, p. 515 - 518 (1984)

The combination of iodine and iodine pen...

Rhodium-Catalyzed Hydrocarboxylation: Mechanistic Analysis Reveals Unusual Transition State for Carbon-Carbon Bond Formation

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, p. 941 - 948 (2018)

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Selective oxidation of α-hydroxy esters ...

Heterogeneous Esterification from α-Hydroxy Ketone and Alcohols through a Tandem Oxidation Process over a Hydrotalcite-Supported Bimetallic Catalyst

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Heterogeneous aerobic oxidative esterifi...

Unraveling two pathways for NHPI-mediated electrocatalytic oxidation reaction

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Two pathways for N-hydroxyphthalimide (N...

Electrochemical two-electron oxygen reduction reaction (ORR) induced aerobic oxidation of α-diazoesters

Chen, Liang,Gao, Meng,Lu, Cuifen,Ma, Chao,Ruan, Mengyao,Wen, Ziyang,Yang, Fan,Yang, Guichun

, p. 2168 - 2171 (2022/02/17)

Electrochemical oxygen reduction reactio...

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An efficient copper-catalyzed tandem oxi...

Pyridinium Chlorochromate Supported on Montmorillonite–KSF as a Versatile Oxidant under Ball Milling Conditions

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15206-55-0 Process route

methanol
67-56-1

methanol

2,2,2-trichloroacetophenone
2902-69-4

2,2,2-trichloroacetophenone

benzoic acid methyl ester
93-58-3,5705-52-2,80226-58-0

benzoic acid methyl ester

methyl 2-oxo-2-phenylacetate
15206-55-0

methyl 2-oxo-2-phenylacetate

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
Conditions Yield
for 16.5h; Irradiation;
6.4%
6%
22.7%
at 25 ℃; for 1h; Product distribution; Mechanism; Irradiation; Effects of oxygen, ring substituents, quenching, (piperylene) and sensitization, (benzophenone).;
10.6 % Chromat.
9.7 % Chromat.
12.3 % Chromat.
2,2,2-trichloroacetophenone
2902-69-4

2,2,2-trichloroacetophenone

benzoic acid methyl ester
93-58-3,5705-52-2,80226-58-0

benzoic acid methyl ester

methyl 2-oxo-2-phenylacetate
15206-55-0

methyl 2-oxo-2-phenylacetate

2,2-dichloroacetophenone
2648-61-5

2,2-dichloroacetophenone

Conditions
Conditions Yield
In methanol; for 16.5h; Irradiation;
22.7%
6.4%
6%

15206-55-0 Upstream products

  • 613-90-1
    613-90-1

    benzoyl cyanide

  • 67-56-1
    67-56-1

    methanol

  • 4358-87-6
    4358-87-6

    (RS)-methyl mandelate

  • 3558-61-0
    3558-61-0

    methyl 2-methoxy-2-phenylacetate

15206-55-0 Downstream products

  • 408307-13-1
    408307-13-1

    3-cyano-2-hydroxy-2-phenyl-succinic acid dimethyl ester

  • 38132-39-7
    38132-39-7

    methyl benzoylformate semicarbazone

  • 611-73-4
    611-73-4

    Benzoylformic acid

  • 23102-13-8
    23102-13-8

    methyl benzoyl formate phenylhydrazone

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