606-28-0

  • Product NameMethyl 2-benzoylbenzoate
  • Molecular FormulaC15H12O3
  • Molecular Weight240.258
  • Purity99%
  • AppearanceSolid.
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Product Details

Quick Details

  • CasNo: 606-28-0
  • Molecular Formula: C15H12O3
  • Appearance: Solid.
  • Purity: 99%

Excellent chemical plant bulk supply Methyl 2-benzoylbenzoate 606-28-0

  • Molecular Formula:C15H12O3
  • Molecular Weight:240.258
  • Appearance/Colour:Solid. 
  • Vapor Pressure:0Pa at 20℃ 
  • Melting Point:48-53 °C(lit.) 
  • Refractive Index:1.5740 (estimate) 
  • Boiling Point:351.5 °C at 760 mmHg 
  • Flash Point:154.4 °C 
  • PSA:43.37000 
  • Density:1.169 g/cm3 
  • LogP:2.70420 

Methyl 2-benzoylbenzoate(Cas 606-28-0) Usage

Preparation

Methyl-2-benzoylbenzoate can be synthesized from the reaction between corresponding 2-substituted benzoic acid and thionyl chloride in methanol.

Flammability and Explosibility

Nonflammable

General Description

Methyl-2-benzoylbenzoate is a 2-acylarylcarboxylate. It can undergo asymmetric transfer hydrogenation reaction in propanol in the presence of a Ruthenium catalyst. Methyl-2-benzoylbenzoate is formed as one of the reaction products during the reaction between methyl benzoate and lithium 2,2,6,6-tetramethylpiperidide (LiTMP) at -117°C.

InChI:InChI=1/C15H12O3/c1-18-15(17)13-10-6-5-9-12(13)14(16)11-7-3-2-4-8-11/h2-10H,1H3

606-28-0 Relevant articles

EFFICIENT AND SELECTIVE ROUTE FOR THE SYNTHESIS OF ALKYL 2-BENZOYLBENZOATE

-

Paragraph 0027, (2021/08/27)

A method for preparing an alkyl 2-benzoy...

Aromatization as an Impetus to Harness Ketones for Metallaphotoredox-Catalyzed Benzoylation/Benzylation of (Hetero)arenes

Chen, Ting-Wei,Cheng, Cheng-Ku,Chiu, Cheng-Chau,Huang, Pin-Gong,Lee, Shao-Chi,Lee, Yi-Hsin,Li, Li-Yun,Liao, Hsuan-Hung,Lin, Heng-Bo,Tsai, Zong-Nan,Tsao, Yong-Ting,Yang, Chung-Hsin

supporting information, (2022/01/04)

Herein we report ketones as feedstock ma...

Acyl radicals from α-keto acids using a carbonyl photocatalyst: Photoredox-catalyzed synthesis of ketones

Zhu, Da-Liang,Wu, Qi,Young, David James,Wang, Hao,Ren, Zhi-Gang,Li, Hong-Xi

supporting information, p. 6832 - 6837 (2020/10/12)

Acyl radicals have been generated from α...

Metal-Free Arylation-Lactonization Sequence of γ-Alkenoic Acids Using Anilines as Aryl Radical Precursors

Felipe-Blanco, Diego,Gonzalez-Gomez, Jose C.

, p. 7735 - 7744 (2019/12/24)

The presence of salicylic acid (10 mol-%...

606-28-0 Process route

o-iodo-methyl-benzoic acid
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o-iodo-methyl-benzoic acid

molybdenum hexacarbonyl
13939-06-5,199620-15-0

molybdenum hexacarbonyl

phenylboronic acid
98-80-6

phenylboronic acid

methyl o-benzoylbenzoate
606-28-0

methyl o-benzoylbenzoate

Conditions
Conditions Yield
With C35H20F34NO3(1-)*Pd(2+)*Cl(1-); N-ethyl-N,N-diisopropylamine; In water; at 140 ℃; for 0.2h; Reagent/catalyst; Concentration; Temperature; Catalytic behavior; Microwave irradiation;
73%
With palladium diacetate; potassium carbonate; In methoxybenzene; at 140 ℃; for 12h;
60%
3-methoxy-3-phenyl-phthalide
7335-63-9

3-methoxy-3-phenyl-phthalide

methyl o-benzoylbenzoate
606-28-0

methyl o-benzoylbenzoate

Conditions
Conditions Yield
With methanesulfonic acid; In toluene; for 6h; Reflux;
99.2%

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